Home    Company News    Analysis on the raw materials and physical properties of H-containing silicone oil

Analysis on the raw materials and physical properties of H-containing silicone oil

Hits: 802 img

H-containing silicone oil is one of the main types of silicone functional groups in silicone products. Due to the different structures and preparation methods of H-containing monomers, they can be divided into three types: partially H-containing, all H-containing and branched H-containing. According to the chemical properties of the silicon-hydrogen bond, it is the main raw material for modified silicone oil to synthesize other organic silicon products and organic products.
The H content in silicone oil is generally between 0.8~1.5%, and the viscosity is about 10~50 (molecular weight is within 2000)
According to the requirements of modified silicone oil products, this method is adjusted from high H content silicone oil (0.8~1.5%) to any low H content and arbitrary viscosity silicone oil. According to the chemical structure of the silicon-oxygen bond, the catalyst for adjustment (catalytic rearrangement) can be acid or alkali. However, the Si-H bond is active to alkali and prone to hydrolysis and dehydrogenation to make it hinge, so the acid that catalyzes the rearrangement is used as the catalyst, and the alkali is used as the neutralizer. Since the catalytic rearrangement reaction needs to be carried out under mild conditions (otherwise it will cause H loss), the temperature control of the reaction process is stricter.

The raw materials and physical properties of H-containing silicone oil:
1. Silicone oil containing H
a. Structural formula:

Where: m>n, m and n are positive integers, m and n are random arrangement
b. Physical properties: colorless or slightly yellow transparent liquid, soluble in gasoline, benzene and other solvents, easy to hinge under the catalysis of metal salt and alkali, long-term exposure to the air, loss of hydrogen and increased viscosity.
c. Product technical indicators:
Appearance: colorless or slightly yellow transparent oily liquid;
Specific gravity: 0.98~1.1 (25/25℃)
Viscosity: 10~50 (25℃C.S)
H content (%): 0.8~1.5
Refractive index (25℃): 1.390~1.410

Online QQ Service, Click here

QQ Service

Wechat Service